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|Section8= }} Ceric ammonium nitrate (CAN) is the inorganic compound with the formula (NH4)2Ce(NO3)6. This orange-red, water-soluble cerium salt is a specialised oxidizing agent in organic synthesis and a standard oxidant in quantitative analysis. ==Preparation, properties, and structure== The anion is generated by dissolving in hot concentrated HNO3. The salt consists of the anion and a pair of NH4+ counter ions. The ammonium ions are not involved in the oxidising reactions of this salt. In the anion each nitrate group is chelated to the cerium atom in a bidentate manner as shown below: : The anion has Th (idealized Oh) molecular symmetry. The CeO12 core defines an icosahedron. Ce4+ is a strong one-electron oxidizing agent. In terms of its redox potential (E° ~ 1.61 V vs. N.H.E.) it is even stronger oxidizing agent than Cl2 (E° ~ 1.36 V). Few shelf-stable reagents are stronger oxidants. In the redox process Ce(IV) is converted to Ce(III), a one-electron change, signaled by the fading of the solution color from orange to a pale yellow (providing that the substrate and product are not strongly colored). 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Ceric ammonium nitrate」の詳細全文を読む スポンサード リンク
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